Maybe a pin hole or hairline crack that hasn't been located yet. You stated the overflow coolant tank boiled over? If so, something is definitely going on.
I can't say for certain that it did considering that the top and sides of the tank weren't really all that wet, but if it wasn't that then I don't know how else all that coolant got down into the driver's side wheel well. Level in the tank now is still a little higher than it was when I found the leak, but it doesn't have as much as it should considering that I filled the radiator, filled the tank to the line, started the engine with the cap off, let the fluid recede into the radiator, then put more in. Level is a little short of the cold fill line. Not surprising since it was pretty clear that a fair amount ran down into the wheel well.
A little tidbit that I'm not sure is important, but....when I first popped the cap on the radiator after that short run to pick up the tabs and coolant, I noticed that the coolant that I could see down inside the radiator looked a bit frothy. Not loads of foam or anything, but the coolant definitely looked a little aerated. I figured with the gurgling that I had air in the system and that air makes froth, so I wasn't exactly alarmed even though that didn't seem quite right to me either.
I'm at the Ford dealer now getting an oil change. Asked them to see if they can visually determine where the leak is coming from while they have it on the lift, but I'm sure they'll end up telling me that I need a pressure test. Will probably go ahead and do it.
